低场核磁共振与近红外联用仪器的研发与应用
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TH 一89

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国家重点研发计划(2018YFE0196600)项目资助


Development and application of low-field nuclear magnetic resonance and near-infrared combined instrument
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    摘要:

    为弥补单一低场核磁共振分析仪或单一近红外光谱仪器能够检测到的信息有限、分离式采样操作繁琐耗时的缺点, 通过研究近红外所用透射式光纤与低场核磁主频21 M、线圈直径25 mm 的探头组合,研发了一款能够同位、同步采样,实现 信息互补的联用分析仪。性能测试结果表明,低场核磁均匀区长度大于25 mm, 近红外光谱标准偏差小于0.003,其他各项测 试结果均符合应用技术要求。最后以84个柴油样品在该联用仪器上进行采样分析试验,以柴油的50%回收温度和密度建立 模型,结果表明,经过特征提取、数据融合的检测模型分别优于基于低场核磁共振与近红外单一数据集的检测模型。由此可 见该联用仪器在柴油分析中具有信息互补的趋势,在石油产品、食品农业、生物医药等检测领域具有实际应用意义与推广 价值。

    Abstract:

    In order to make up for the shortcomings of limited information that can be detected by a single low-field nuclear magnetic resonance analyzer or a single near-infrared spectroscopy instrument,and the cumbersome and time- consuming separation of sampling operations,by studying the transmission optical fiber used in near-infrared and low- field nuclear magnetic resonance with a main frequency of 21 M and acoil diameter with a combination of 25 mm probes, a joint analyzer capable of co-location and synchronous sampling to achieve complementary information has been developed.The performance test results show that the length of the low-field NMR homogeneous region is greater than 25 mm,the standard deviation of the near-infrared spectrum is less than 0.003,and other test results meet the application technical requirements.Finally,84 diesel samples were sampled and analyzed on the combined instrument, and the model was established based on the 50%recovery temperature and density of diesel.The results showed that the detection models based on feature extraction and data fusion were better than those based on low-field NMR and one detection model for a near-infrared single dataset.It can be seen that the combined instrument has a trend of information complementation in the analysis of diesel oil,and has practical application significance and promotion value in the detection fields of petroleum products,food agriculture,and biomedicine.

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曾英杰,卢 丙,杨 亮,杨 培 强,陆 道 礼,陈 斌.低场核磁共振与近红外联用仪器的研发与应用[J].国外电子测量技术,2023,42(3):88-94

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  • 在线发布日期: 2024-10-22
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